Internal cation mobilities in molten lithium - Potassium fluoride

Haruaki Matsuura; Ryo Ohashi; Pao-Hwa Chou; Ryuzo Takagi; Haruaki MATSUURA

doi:10.5796/electrochemistry.74.822

Internal cation mobilities in molten lithium - Potassium fluoride

Haruaki Matsuura, Ryo Ohashi, Pao-Hwa Chou, Ryuzo Takagi, Haruaki MATSUURA

Department of Nuclear Safety Engineering

Research output: Contribution to journal › Misc

Abstract

Relative differences between internal cation mobilities in molten (Li, K) F have been measured by countercurrent electromigration (Klemm method) at 1023 K. Internal mobilities of K+ are larger than those of Li+ in all composition on which we have measured so far. More striking feature is that the isotherms have minimum of mobilities at ca. x(K) = 0.5. The local structural parameters would be highly related to the ionic conduction behavior in molten fluorides.

Translated title of the contribution	Internal cation mobilities in molten lithium - Potassium fluoride
Original language	American English
Pages (from-to)	822 - 824
Journal	Electrochemistry
Volume	74
Issue number	10
DOIs	https://doi.org/10.5796/electrochemistry.74.822
State	Published - Oct 2006

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10.5796/electrochemistry.74.822

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title = "Internal cation mobilities in molten lithium - Potassium fluoride",

abstract = "Relative differences between internal cation mobilities in molten (Li, K) F have been measured by countercurrent electromigration (Klemm method) at 1023 K. Internal mobilities of K+ are larger than those of Li+ in all composition on which we have measured so far. More striking feature is that the isotherms have minimum of mobilities at ca. x(K) = 0.5. The local structural parameters would be highly related to the ionic conduction behavior in molten fluorides.",

author = "\{Haruaki Matsuura\} and \{Ryo Ohashi\} and \{Pao-Hwa Chou\} and \{Ryuzo Takagi\} and Haruaki MATSUURA",

year = "2006",

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doi = "10.5796/electrochemistry.74.822",

language = "American English",

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pages = "822 -- 824",

journal = "Electrochemistry",

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T1 - Internal cation mobilities in molten lithium - Potassium fluoride

AU - Haruaki Matsuura, null

AU - Ryo Ohashi, null

AU - Pao-Hwa Chou, null

AU - Ryuzo Takagi, null

AU - MATSUURA, Haruaki

PY - 2006/10

Y1 - 2006/10

N2 - Relative differences between internal cation mobilities in molten (Li, K) F have been measured by countercurrent electromigration (Klemm method) at 1023 K. Internal mobilities of K+ are larger than those of Li+ in all composition on which we have measured so far. More striking feature is that the isotherms have minimum of mobilities at ca. x(K) = 0.5. The local structural parameters would be highly related to the ionic conduction behavior in molten fluorides.

AB - Relative differences between internal cation mobilities in molten (Li, K) F have been measured by countercurrent electromigration (Klemm method) at 1023 K. Internal mobilities of K+ are larger than those of Li+ in all composition on which we have measured so far. More striking feature is that the isotherms have minimum of mobilities at ca. x(K) = 0.5. The local structural parameters would be highly related to the ionic conduction behavior in molten fluorides.

U2 - 10.5796/electrochemistry.74.822

DO - 10.5796/electrochemistry.74.822

M3 - Misc

SN - 1344-3542

VL - 74

SP - 822

EP - 824

JO - Electrochemistry

JF - Electrochemistry

IS - 10

ER -

Internal cation mobilities in molten lithium - Potassium fluoride

Abstract

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